Thermoelectric figure of merit of tau-type conductors of several donors

Dimensionless thermoelectric figure of merit $ZT$ is investigated for two-dimensional organic conductors $\tau-(EDO-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$, $\tau$-(EDT-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$and$\tau$-(P-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$ ($y \le 0.875$), respectively. The $ZT$ values were estimated by measuring electrical resistivity, thermopower and thermal conductivity simultaneously. The largest $ZT$ is 2.7 $\times$ 10$^{-2}$ at 155 K for $\tau-(EDT-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$, 1.5 $\times$ 10$^{-2}$ at 180 K for $\tau-(EDO-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$ and 5.4 $\times$ 10$^{-3}$ at 78 K for $\tau-(P-S,S-DMEDT-TTF)_2(AuI_2)_{1+y}$, respectively. Substitution of the donor molecules fixing the counter anion revealed EDT-S,S-DMEDT-TTF is the best of the three donors to obtain larger $ZT$.Comment: proceedings of ISCOM 2009 (to be published in Physica B

Estimation of Regional Evapotranspiration Using Remotely Sensed Land Surface Temperature. Part 1: Measurement of Evapotranspiration at the Environmental Research Center and Determination of Priestley-taylor Parameter

In order to study the distribution of evapotranspiration in the humid region using remote sensing technology, the parameter (alpha) in the Priestley-Taylor model was determined. The daily means of the parameter alpha = 1.14 can be available from summer to autumn and alpha = to approximately 2.0 in winter. The results of the satellite and the airborne sensing done on 21st and 22nd January, 1983, are described. Using the vegetation distribution in the Tsukuba Academic New Town, as well as the radiation temperature obtained by remote sensing and the radiation data observed at the ground surface, the evapotranspiration was calculated for each vegetation type by the Priestley-Taylor method. The daily mean evapotranspiration on 22nd January, 1983, was approximately 0.4 mm/day. The differences in evapotranspiration between the vegetation types were not detectable, because the magnitude of evapotranspiration is very little in winter

Estimation of Regional Evapotranspiration Using Remotely Sensed Land Surface Temperature. Part 2: Application of Equilibrium Evaporation Model to Estimate Evapotranspiration by Remote Sensing Technique

In a humid region like Japan, it seems that the radiation term in the energy balance equation plays a more important role for evapotranspiration then does the vapor pressure difference between the surface and lower atmospheric boundary layer. A Priestley-Taylor type equation (equilibrium evaporation model) is used to estimate evapotranspiration. Net radiation, soil heat flux, and surface temperature data are obtained. Only temperature data obtained by remotely sensed techniques are used

Absolute Transition Probabilities of Lines in the Spectra of Astrophysical Atoms, Molecules, and Ions

Progress in the investigation of absolute transition probabilities (A-values or F values) for ultraviolet lines is reported. A radio frequency ion trap was used for measurement of transition probabilities for intersystem lines seen in astronomical spectra. The intersystem line at 2670 A in Al II, which is seen in pre-main sequence stars and symbiotic stars, was studied

Absolute absorption cross sections of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm

An account is given of progress of work on absorption cross section measurements of ozone at 300 K, 228 K and 195 K in the wavelength region 185-240 nm. In this wavelength region, the penetration of solar radiation into the Earth's atmosphere is controlled by O2 and O3. The transmitted radiation is available to dissociate trace species such as halocarbons and nitrous oxide. We have recently measured absolute absorption cross sections of O3 in the wavelength region 240-350 nm (Freeman et al., 1985; Yoshino et al., 1988). We apply these proven techniques to the determination of the absorption cross section of O3 at 300 K, 228 K and 195 K throughout the wavelength region 185-240 nm. A paper titled 'Absolute Absorption Cross Section Measurements of Ozone in the Wavelength Region 185-254 nm and the Temperature Dependence' has been submitted for publication in the Journal of Geophysical Research

Temperature Chaos and Bond Chaos in the Edwards-Anderson Ising Spin Glass : Domain-Wall Free-Energy Measurements

Domain-wall free-energy $\delta F$, entropy $\delta S$, and the correlation function, $C_{\rm temp}$, of $\delta F$ are measured independently in the four-dimensional $\pm J$ Edwards-Anderson (EA) Ising spin glass. The stiffness exponent $\theta$, the fractal dimension of domain walls $d_{\rm s}$ and the chaos exponent $\zeta$ are extracted from the finite-size scaling analysis of $\delta F$, $\delta S$ and $C_{\rm temp}$ respectively well inside the spin-glass phase. The three exponents are confirmed to satisfy the scaling relation $\zeta=d_{\rm s}/2-\theta$ derived by the droplet theory within our numerical accuracy. We also study bond chaos induced by random variation of bonds, and find that the bond and temperature perturbations yield the universal chaos effects described by a common scaling function and the chaos exponent. These results strongly support the appropriateness of the droplet theory for the description of chaos effect in the EA Ising spin glasses.Comment: 4 pages, 6 figures; The title, the abstract and the text are changed slightl

Determination of spectroscopic properties of atmospheric molecules from high resolution vacuum ultraviolet cross section and wavelength measurements

Progress is given on work on: cross section measurements in the transmission window regions of the Schumann-Runge bands of oxygen; the determinations of predissociation linewidths; the theoretical calculation of band oscillator strengths of the Schumann-Runge absorption bands of O-16O-18; the determination of molecular spectroscopic constants; and the combined Herzberg continuum cross sections. The experimental investigations relevant to the cross section measurements, predissociation linewidths, and molecular spectroscopic constants are effected at high resolution with a 6.65 m scanning spectrometer which is, by virtue of its small instrumental width (FWHM = 0.0013 nm), suitable for cross section measurements of molecular bands with discrete rotational structure. Such measurements are needed for accurate calculations of the stratospheric production of atomic oxygen and heavy ozone formed following the photo-predissociation of O-16O-18 by solar radiation penetrating between the absorption lines of O-16(sub 2)

Scaling Analysis of Domain-Wall Free-Energy in the Edwards-Anderson Ising Spin Glass in a Magnetic Field

The stability of the spin-glass phase against a magnetic field is studied in the three and four dimensional Edwards-Anderson Ising spin glasses. Effective couplings and effective fields associated with length scale L are measured by a numerical domain-wall renormalization group method. The results obtained by scaling analysis of the data strongly indicate the existence of a crossover length beyond which the spin-glass order is destroyed by field H. The crossover length well obeys a power law of H which diverges as H goes to zero but remains finite for any non-zero H, implying that the spin-glass phase is absent even in an infinitesimal field. These results are well consistent with the droplet theory for short-range spin glasses.Comment: 4 pages, 5 figures; The text is slightly changed, the figures 3, 4 and 5 are changed, and a few references are adde

Oscillator strengths and line widths of dipole-allowed transitions in ¹⁴N₂ between 89.7 and 93.5 nm

Line oscillator strengths in the 20 electric dipole-allowed bands of ¹⁴N₂ in the 89.7–93.5nm (111480–106950cm⁻¹) region are reported from photoabsorptionmeasurements at an instrumental resolution of ∼6mÅ (0.7cm⁻¹) full width at half maximum. The absorptionspectrum comprises transitions to vibrational levels of the 3pσᵤc′₄¹Σᵤ⁺, 3pπᵤc³Πᵤ, and 3sσgo₃¹ΠᵤRydberg states and of the b′¹Σᵤ⁺ and b¹Πᵤ valence states. The J dependences of band f values derived from the experimental line f values are reported as polynomials in J′(J′+1) and are extrapolated to J′=0 in order to facilitate comparisons with results of coupled Schrödinger-equation calculations. Most bands in this study are characterized by a strong J dependence of the band f values and display anomalous P-, Q-, and R-branch intensity patterns. Predissociation line widths, which are reported for 11 bands, also exhibit strong J dependences. The f value and line width patterns can inform current efforts to develop comprehensive spectroscopic models that incorporate rotational effects and predissociation mechanisms, and they are critical for the construction of realistic atmospheric radiative-transfer models.This work was supported in part by NASA Grant No. NNG05GA03G to Wellesley College and Australian Research Council Discovery Program Grant No. DP0558962

Rotational viscosity in ferroelectric liquid crystals estimated from transient light scattering and dielectric properties

A new method for the estimation of rotational viscosity of ferroelectric liquid crystals using transient light scattering (TSM) is reported. The relation between rotational viscosity, spontaneous polarization, and dielectric dispersion frequency is studied as a function of the racemization. The rotational viscosity is almost independent of spontaneous polarization and there is no obvious correlation between rotational viscosity and dispersion frequency. The dispersion frequency is confirmed to be inversely proportional to the square of the helical pitch. The rotational viscosity calculated from this relation is consistent with that from the new TSM method.This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in M. Ozaki, T. Hatai, K. Nakao, and K. Yoshino, Journal of Applied Physics 65, 3602 (1989) and may be found at https://doi.org/10.1063/1.342639